First off, Super Mario Bros. 3, tied for best game ever, should have been a launch title.
I've wanted to play Earthbound for a long time, and I really hated Nintendo for not bringing the Mother I + II GBA cart here, so I'm really looking forward to that.
Also (in no particular order):
•Star Wars: Rogue Squadron (N64)
•Star Wars: Episode I: Racer (N64)
•Star Wars: Shadows of the Empire (N64)
•Battletoads (NES)
•NHL Hockey or NHL 96 (Genesis)
•Mario Golf and Mario Tennis (N64)
•Flicky (Genesis)
•Harvest Moon 64 (N64)
•Mario Party 3 (N64) (Duel Mode kicks ass)
•Perfect Dark (N64) (I know there's no chance, but let me have my dream)
•Diddy Kong Racing (N64) (though not for a while, we've got too many N64 racers right now)
•F-Zero Expansion Kit (N64)
•Yoshi's Story (N64)
Also, it's not technically Virtual Console, but I'd love a Wii Ware version of Pac Man Vs. that connected to the DS; the upcoming DS version is cool, but I don't know enough people with DSs for it to work enough.